Was your original bulb a
UVB light as well? Or was it just a 100w basking light producing heat? For a 40g enclosure, using 2 - 100w bulbs might produce a bit too much heat for the space. I'm not sure which brand of MVB you have now (they vary in output strength and shape between brands) but generally if you put a 100w MVB about 12'' above the main basking area it will produce adequate UVB.
The trick is then to be providing an appropriate temperature gradient. If your surface temps are around 100 with the MVB at 12'', then that should be all you need. If the temps are too low, then you might want to add either the original bulb for more heat or use a heat projector/ceramic heat emitter to supplement the heat produced by your new MVB.